MATERIAL SAFETY DATA SHEET
Review Date: 04/29/2003
			

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SECTION 1	PRODUCT AND COMPANY  IDENTIFICATION

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PRODUCT:  BR LS Diesel 2

MSDS NUMBER:   401359M - 1
PRODUCT CODE(S):      00432, 00433, 26756

MANUFACTURER ADDRESS:  Motiva Enterprises LLC, P.O. Box 4540, Houston, TX.  
77210-4540

TELEPHONE NUMBERS
Spill Information: (877) 242-7400
Health Information: (877) 504-9351
MSDS Assistance Number:  (877) 276-7285


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SECTION 2	PRODUCT/INGREDIENTS

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CAS#        CONCENTRATION           INGREDIENTS    
Mixture     100 %weight             #2 Diesel 
68814-87-9  0 - 99.99 %weight       Full Range Straight Run Middle Distillate 
64741-59-9  0 - 39.99 %weight       Light Catalytic Cracked Distillate 
71-43-2     0.01 - 0.64 %weight     Benzene 
7704-34-9   0 - 0.04 %weight        Sulfur 


NOTE:   H2S is a naturally occuring constituent in the petroleum stream and is 
not added separately to the product.

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SECTION 3	HAZARDS IDENTIFICATION 

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EMERGENCY OVERVIEW
Appearance & Odor:   Bright and clear liquid (Tax Exempt Diesels - pale red 
liquid). Oil-type odor.
Health Hazards: Hydrogen sulfide (H2S), an extremely flammable and toxic gas, 
may be present.  Causes severe skin irritation.  Toxic and harmful if inhaled. 
 May be harmful or fatal if swallowed. Do not induce vomiting. May cause 
aspiration pneumonitis.
Physical Hazards: Combustible Liquid.  
NFPA Rating (Health, Fire, Reactivity):  2, 2, 0
Hazard Rating:     Least - 0     Slight - 1     Moderate - 2     High - 3    
Extreme - 4

Inhalation:
In applications where vapors (caused by high temperature) or mists (caused by 
mixing or spraying) are created, breathing may cause a mild burning sensation 
in the nose, throat and lungs.  Toxic and harmful if inhaled.  Hydrogen 
Sulfide (H2S) and other hazardous vapors may evolve and collect in the 
headspace of storage tanks or other enclosed vessels.  Hydrogen Sulfide is an 
extremely flammable, toxic gas.  Inhalation of vapors, mist or fumes 
(generated at high temperatures) may cause irritation to the nose, throat and 
respiratory tract.

Eye Irritation:
If irritation occurs, a temporary burning sensation, minor redness, swelling, 
and/or blurred vision may result.

Skin Contact:
Severely irritating to the skin causing pain, redness and swelling.  Other 
adverse effects not expected from brief skin contact.

Ingestion:
This material may be harmful or fatal if swallowed.  Ingestion may result in 
vomiting; aspiration (breathing) of vomitus into lungs must be avoided as even 
small quantities may result in aspiration pneumonitis.  Generally considered 
to have a low order of acute oral toxicity.

Other Health Effects:
Carcinogenic in animal tests.  It is probable that the material causes cancer 
in laboratory animals. 
Material may release hydrogen sulfide (H2S), a highly toxic and extremely 
flammable gas, when heated to 180 Degrees F or higher.  H2S can cause 
irritation of the eyes and respiratory tract, headache, dizziness, nausea, 
vomitting, diarrhea, and pulmonary edema.  The odor ("rotten egg") threshold 
is 0.02 ppm.  Do not depend on sense of smell for warning;  H2S rapidly 
deadens the sense of smell.
Refer to Section 11, Toxicological Information, for specific information on 
the following effects:

Signs and Symptoms:
Irritation as noted above.  Aspiration pneumonitis may be evidenced by 
coughing, labored breathing and cyanosis (bluish skin); in severe cases death 
may occur.

For additional health information, refer to section 11.


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SECTION 4	FIRST AID MEASURES

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Inhalation:
Vaporization of H2S that has been trapped in clothing can be dangerous to 
rescuers.  Maintain respiratory protection to avoid contamination from victim 
to rescuer.  Mechanical ventilation should be used to resuscitate the victim.  
DO NOT attempt to rescue victim unless proper respiratory protection is worn.  
If the victim has difficulty breathing or tightness of the chest, is dizzy, 
vomiting or unresponsive, give 100% oxygen with rescue breathing or CPR as 
required and transport to the nearest medical facility.

Skin:
Remove contaminated clothing.  Flush with large amounts of water for at least 
15 minutes and follow by washing with soap if available.  If redness, 
swelling, pain and/or blisters occur, transport to the nearest medical 
facility for additional treatment.

Eye:
Flush eyes with plenty of water while holding eyelids open.  Rest eyes for 30 
minutes.  If redness, burning, blurred vision or swelling occur, transport to 
nearest medical facility for additional treatment.

Ingestion:
DO NOT take internally.    In general no treatment is necessary unless large 
quantities are swallowed, however, get medical advice.  Have victim rinse 
mouth out with water, then drink sips of water to remove taste from mouth.  If 
vomiting occurs spontaneously, keep head below hips to prevent aspiration.

Note to Physician:
If more than 2.0ml/kg body weight has been ingested and vomiting has not 
occurred, emesis should be induced with supervision.  Keep victim's head below 
hips to prevent aspiration.  If symptoms such as loss of gag reflex, 
convulsions, or unconsciousness occur before emesis, gastric lavage using a 
cuffed endotracheal tube should be considered.


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SECTION 5	FIRE FIGHTING MEASURES

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Flash Point [Method]:     >125 F/>51.67 C [ Closed Cup]
Autoignition Temperature:     500 F/260 C
Flammability in Air:     0.5 - 4.4 %volume

Extinguishing Media:
Material will float and can be re-ignited on surface of water.  Use water fog, 
'alcohol foam', dry chemical or carbon dioxide (CO2) to extinguish flames.  Do 
not use a direct stream of water.  

Fire Fighting Instructions:
CAUTION!  COMBUSTIBLE.  Clear fire area of all non-emergency personnel.  Do 
not enter confined fire space without full bunker gear (helmet with face 
shield, bunker coats, gloves and rubber boots), including a positive pressure, 
NIOSH approved, self-contained breathing apparatus.  Cool surrounding 
equipment, fire-exposed containers and structures with water.  Container areas 
exposed to direct flame contact should be cooled with large quantities of 
water (500 gallons water per minute flame impingement exposure) to prevent 
weakening of container structure.


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SECTION 6	ACCIDENTAL RELEASE MEASURES

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Protective Measures:
CAUTION!  COMBUSTIBLE.  Eliminate potential sources of ignition.  Handling 
equipment must be bonded and grounded to prevent sparking.

Wear appropriate personal protective equipment when cleaning up spills.  Refer 
to Section 8.

Spill Management:
Shut off source of leak if safe to do so.  Dike and contain spill.

FOR LARGE SPILLS: Remove with vacuum truck or pump to storage/salvage vessels.

FOR SMALL SPILLS:  Soak up residue with an absorbent such as clay, sand or 
other suitable material.  Place in non-leaking container and seal tightly for 
proper disposal.

Reporting:
CERCLA: Product is covered by EPA's Comprehensive Environmental Response, 
Compensation and Liability Act (CERCLA) petroleum exclusion.  Releases to air, 
land, or water are not reportable under CERCLA (Superfund).

CWA: This product is an oil as defined under Section 311 of EPA's Clean Water 
Act (CWA). Spills into or leading to surface waters that cause a sheen must be 
reported to the National Response Center, 1-800-424-8802.


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SECTION 7	HANDLING AND STORAGE

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Precautionary Measures:
CAUTION!  COMBUSTIBLE.  Do not breathe material.  Keep container closed.  Use 
only with adequate ventilation.  Avoid heat, open flames, including pilot 
lights, and strong oxidizing agents.  Use explosion-proof ventilation to 
prevent vapor accumulation.  Ground all handling equipment to prevent 
sparking.  Avoid contact with eyes, skin and clothing.  Wash thoroughly after 
handling.

Material may release hydrogen sulfide (H2S), a highly toxic and extremely 
flammable gas, when heated to 180 Degrees F or higher.  H2S may collect in the 
headspace of the container.

Handling:
Surfaces that are sufficiently hot may ignite liquid material.

Storage:
Keep liquid and vapor away from heat, sparks and flame.  Extinguish pilot 
lights, cigarettes and turn off other sources of ignition prior to use and 
until all vapors have dissipated. Use explosion-proof ventilation indoors and 
in laboratory settings.  

Container Warnings:
Keep containers closed when not in use.  Containers, even those that have been 
emptied, can contain explosive vapors.  Do not cut, drill, grind, weld or 
perform similar operations on or near containers.


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SECTION 8	EXPOSURE CONTROLS/PERSONAL PROTECTION

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Benzene   ACGIH TLV  TWA: 0.5 ppmv  STEL: 2.5 ppmv    Notation: Skin
Benzene   OSHA PEL  TWA: 1 ppmv  STEL: 5 ppmv    
Diesel Fuel, as total hydrocarbons   ACGIH TLV  TWA: 100 mg/m3      

Carbon dioxide   ACGIH - TLV  TWA: 5000 ppmm  STEL: 30000 ppmm    
Carbon dioxide   OSHA - PEL    STEL: 30000 ppmm    
Carbon dioxide   OSHA - PEL_IS  TWA: 10000 ppmm      
Carbon monoxide   OSHA - PEL  TWA: 35 ppmv    Ceiling: 200 ppmv  
Carbon monoxide              Combustion                 


EXPOSURE CONTROLS
Adequate explosion-proof ventilation to control airborne concentrations.


PERSONAL PROTECTION
Personal protective equipment (PPE) selections vary based on potential 
exposure conditions such as handling practices, concentration and ventilation. 
 Information on the selection of eye, skin and respiratory protection for use 
with this material is provided below.

Eye Protection:
Chemical Goggles - If liquid contact is likely., or Safety glasses with side 
shields

Skin Protection:
Use protective clothing which is chemically resistant to this material.  
Selection of protective clothing depends on potential exposure conditions and 
may include gloves, boots, suits and other items.  The selection(s) should 
take into account such factors as job task, type of exposure and durability 
requirements.

Published literature, test data and/or glove and clothing manufacturers 
indicate the best protection is provided by:
Neoprene, or Nitrile Rubber
Respiratory Protection:
If engineering controls do not maintain airborne concentrations to a level 
which is adequate to protect worker health, an approved respirator must be 
worn.  Respirator selection, use and maintenance should be in accordance with 
the requirements of the OSHA Respiratory Protection Standard, 29 CFR 1910.134.

Types of respirator(s) to be considered in the selection process include:
Supplied-Air Respirator.  Air-Purifying Respirator for Organic Vapors.  
Self-contained breathing apparatus for use in environments with unknown 
concentrations or emergency situations.



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SECTION 9	PHYSICAL AND CHEMICAL PROPERTIES

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Appearance & Odor:  Bright and clear liquid (Tax Exempt Diesels - pale red 
liquid). Oil-type odor.
Substance Chemical Family:    Petroleum Hydrocarbon, Fuel Oil
Appearance:   Bright and clear liquid (Tax Exempt Diesels - pale red liquid).

Auto Ignition Temperature:   500 F

Flammability in Air:   0.5 - 4.4 %volume

Flash Point:  > 125 F [Closed Cup]

Specific Gravity:   0.85 Typical

Stability:   Stable

Vapor Pressure:   0.02 mmHg Typical [Calculated]

Viscosity:   1.9 - 4.1 cSt @ 40 C


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SECTION 10	REACTIVITY AND STABILITY

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Stability:
Material is stable under normal conditions.

Conditions to Avoid:
Avoid heat and open flames.

Materials to Avoid:
Avoid contact with strong oxidizing agents.

Hazardous Decomposition Products:

Thermal decomposition products are highly dependent on combustion conditions.  
A complex mixture of airborne solids, liquids and gases will evolve when this 
material undergoes pyrolysis or combustion. Aldehydes, Carbon Monoxide, Carbon 
Dioxide, Ketonesand other unidentified organic compounds may be formed upon 
combustion.


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SECTION 11	TOXICOLOGICAL INFORMATION

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Acute Toxicity
  Dermal LD50  > 5 ml/kg(Rabbit)   OSHA: Non-Toxic  Based on similar 
material(s)
  Eye Irritation  Non-Irritating [Rabbit]   OSHA: Non-Irritating  Based on 
similar material(s)
  Oral LD50  9 ml/kg(Rat)   OSHA: Non-Toxic  Based on similar material(s)
  Skin Irritation  Extremely irritating [Rabbit]   OSHA: Irritating  Based on 
similar material(s)
Carcinogenicity Classification
#2 Diesel
   NTP: No  IARC: No  ACGIH: No  OSHA: No
Benzene
   NTP: Yes  IARC: Carcinogen (1)  ACGIH: A1  OSHA: Yes
Light Catalytic Cracked Distillate
   NTP: No  IARC: Possible Carcinogen (2B)  ACGIH: No  OSHA: No
Carcinogenicity
Related materials have caused the development of skin tumors in lifetime mouse 
skin painting studies. However, these tumors have a long latency period and 
may be associated with the repeated severe irritation caused by the test 
materials. Prolonged and repeated exposure to high concentrations (10s to 100s 
ppm) of benzene may cause serious injury to blood-forming organs and is 
associated with anemia (depletion of blood cells) and is linked to the later 
development of acute myelogenous leukemia (AML).

Genotoxicity
A closely related component (Hydrodesulfurized Middle Distillate) did not 
cause detectable mutations in two different in vivo (live animal) studies.  
Some evidence of genotoxicity was seen in separate in vitro (test tube) 
studies, usually in cases where the test material was metabolically activated.

 

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SECTION 12	ECOLOGICAL INFORMATION

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Environmental Impact Summary:
There is no ecological data available for this product.  


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SECTION 13	DISPOSAL CONSIDERATIONS

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RCRA Information:

Under RCRA, it is the responsibility of the user of the material to determine, 
at the time of the disposal, whether the material meets RCRA criteria for 
hazardous waste.  This is because material uses, transformations, mixtures, 
processes, etc. may affect the classification.  Refer to the latest EPA, state 
and local regulations regarding proper disposal.


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SECTION 14	TRANSPORT INFORMATION

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US Department of Transportation Classification

Proper Shipping Name:			Diesel Fuel
Identification Number:			NA1993	 	
Hazard Class/Division:			Combustible Liquid
Packing Group:				III	


Hazardous Substance/Material RQ:			Benzene / 1546.2005 lbs	

Oil:  This product is an oil under 49CFR (DOT) Part 130. If shipped by rail or 
highway in a tank with a capacity of 3500 gallons or more, it is subject to 
these requirements.  Mixtures or solutions containing 10% or more of this 
product may also be subject to this rule.

Emergency Response Guide #128

International Air Transport Association
Hazard Class/Division:			3 (Flammable Liquid)
Identification Number:			UN1202
Packing Group:				III
Proper Shipping Name:			Diesel Fuel	

International Maritime Organization Classification
Hazard Class/Division:			3 (Flammable Liquid)
Identification Number:			UN1202
Packing Group:				III
Proper Shipping Name:			Diesel Fuel


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SECTION 15	REGULATORY INFORMATION

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FEDERAL REGULATORY STATUS

OSHA  Classification:
Product is hazardous according to the OSHA Hazard Communication Standard, 29 
CFR 1910.1200.

Ozone Depleting Substances (40 CFR 82 Clean Air Act):
This material does not contain nor was it directly manufactured with any Class 
I or Class II ozone depleting substances.

Superfund Amendment & Reauthorization Act (SARA) Title III:

SARA Extremely Hazardous Substances (302/304): 
Hydrogen sulfide              RQ 100 lbs  Reportable Spill =>  711013 lbs or 
100334 gal 

SARA Hazard Categories (311/312):
Immediate Health:YES   Delayed Health:YES   Fire:YES   Pressure:NO   
Reactivity:NO 

SARA Toxic Release Inventory (TRI) (313):
Benzene

Toxic Substances Control Act (TSCA) Status:
This material is listed on the EPA/TSCA Inventory of Chemical Substances.

Other Chemical Inventories:
 Australian AICS,  Canadian DSL,  European EINECS,  Korean Inventory,

State Regulation
The following chemicals are specifically listed by individual states; other 
product specific health and safety data in other sections of the MSDS may also 
be applicable for state requirements.  For details on your regulatory 
requirements you should contact the appropriate agency in your state.


California Safe Drinking Water and Toxic Enforcement Act (Proposition 65).
WARNING: This product contains a chemical(s) known to the State of California 
to cause cancer.

WARNING: This product contains a chemical(s) known to the State of California 
to cause birth defects or other reproductive harm.


New Jersey Right-To-Know Chemical List:
Benzene (71-43-2)  0.01 -  0.64   %weight  Carcinogen 
Benzene (71-43-2)  0.01 -  0.64   %weight  Mutagen 
Light Cat Cracked Distillate  0 -  39.99   %weight  Mutagen 

Pennsylvania Right-To-Know Chemical List:
Benzene (71-43-2)  0.01 -  0.64   %weight  Spec Haz Sub/Env Hazardous 


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SECTION 16	OTHER INFORMATION

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Revision#: 1
Review Date: 04/29/2003
Revision Date: 04/29/2003
Revisions since last change (discussion): This Material Safety Data Sheet 
(MSDS) has been newly created to fully comply with the guidance contained in 
the ANSI MSDS standard (ANSI Z400.1-1998).   We encourage you to take the 
opportunity to read the MSDS and review the information contained therein.


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SECTION 17	LABEL INFORMATION

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READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING OF 
PRODUCT.  THIS LABEL COMPLIES WITH THE REQUIREMENTS OF THE OSHA HAZARD 
COMMUNICATION STANDARD (29 CFR 1910.1200) FOR USE IN THE WORKPLACE. THIS LABEL 
IS NOT INTENDED TO BE USED WITH PACKAGING INTENDED FOR SALE TO CONSUMERS AND 
MAY NOT CONFORM WITH THE REQUIREMENTS OF THE CONSUMER PRODUCT SAFETY ACT OR 
OTHER RELATED REGULATORY REQUIREMENTS.

PRODUCT CODE(S):  00432, 00433, 26756

BR LS Diesel 2

WARNING!

COMBUSTIBLE LIQUID!  MAY BE FATAL IF INHALED.  CAUSES SEVERE SKIN IRRITATION.  
ASPIRATION HAZARD IF SWALLOWED - CAN ENTER LUNGS AND CAUSE DAMAGE.  CONTAINS 
BENZENE WHICH IS A CANCER HAZARD - LINKED TO DEVELOPMENT OF ACUTE MYELOGENOUS 
LEUKEMIA.
Refer to Section 11, Toxicological Information, for specific information on 
the following effects:

Precautionary Measures:   
Avoid heat and open flames.  Hydrogen Sulfide and other hazardous vapors may 
evolve and collect in the headspace of storage tanks or other enclosed 
vessels.  Hydrogen Sulfide is an extremely flammable, toxic gas.  Respiratory 
protection should be worn when venting tanks.  Avoid  breathing of vapors, 
fumes, or mist.  Do not take internally.  Use only with adequate ventilation.  
Avoid contact with eyes, skin and clothing.  Keep container closed when not in 
use.  Wash thoroughly after handling.

FIRST AID
Inhalation:  DO NOT attempt to rescue victim unless proper respiratory 
protection is worn.  Vaporization of H2S that has been trapped in clothing can 
be dangerous to rescuers.  Maintain respiratory protection to avoid 
contamination from victim to rescuer.  Mechanical ventilation should be used 
to resuscitate the victim.  If the victim has difficulty breathing or 
tightness of the chest, is dizzy, vomiting or unresponsive, give 100% oxygen 
with rescue breathing or CPR as required and transport to the nearest medical 
facility.
Skin Contact:  Remove contaminated clothing.  Flush with large amounts of 
water for at least 15 minutes and follow by washing with soap if available.  
If redness, swelling, pain and/or blisters occur, transport to the nearest 
medical facility for additional treatment.
Eye Contact:  Flush eyes with plenty of water while holding eyelids open.  
Rest eyes for 30 minutes.  If redness, burning, blurred vision or swelling 
occur, transport to nearest medical facility for additional treatment.
Ingestion:  DO NOT take internally.    If vomiting occurs spontaneously, keep 
head below hips to prevent aspiration.  Have victim rinse mouth out with 
water, then drink sips of water to remove taste from mouth.  In general no 
treatment is necessary unless large quantities are swallowed, however, get 
medical advice.

FIRE

In case of fire,   Use water fog, 'alcohol foam', dry chemical or carbon 
dioxide (CO2) to extinguish flames.  Do not use a direct stream of water.    
Material will float and can be re-ignited on surface of water.
SPILL OR LEAK
Dike and contain spill.
FOR LARGE SPILLS: Remove with vacuum truck or pump to storage/salvage vessels.

FOR SMALL SPILLS:  Soak up residue with an absorbent such as clay, sand or 
other suitable material.  Place in non-leaking container and seal tightly for 
proper disposal.

CONTAINS: Full Range Straight Run Middle Distillate, 68814-87-9; Light 
Catalytic Cracked Distillate, 64741-59-9; Benzene, 71-43-2; Sulfur, 7704-34-9

NFPA Rating (Health, Fire, Reactivity):   2, 2, 0

TRANSPORTATION

US Department of Transportation Classification

Proper Shipping Name:			Diesel Fuel
Identification Number:			NA1993	 	
Hazard Class/Division:			Combustible Liquid
Packing Group:				III	


Hazardous Substance/Material RQ:			Benzene / 1546.2005 lbs	

Oil:  This product is an oil under 49CFR (DOT) Part 130. If shipped by rail or 
highway in a tank with a capacity of 3500 gallons or more, it is subject to 
these requirements.  Mixtures or solutions containing 10% or more of this 
product may also be subject to this rule.

Emergency Response Guide #128


California Safe Drinking Water and Toxic Enforcement Act (Proposition 65).
WARNING: This product contains a chemical(s) known to the State of California 
to cause cancer.

WARNING: This product contains a chemical(s) known to the State of California 
to cause birth defects or other reproductive harm.

 


Name and Address   
          Motiva Enterprises LLC
          P.O. Box 4540
          Houston, TX  77210-4540

ADMINISTRATIVE INFORMATION
MANUFACTURER ADDRESS:  Motiva Enterprises LLC, P.O. Box 4540, Houston, TX.  
77210-4540

THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON THE DATA AVAILABLE TO 
US AT THIS TIME, AND IS BELIEVED TO BE ACCURATE BASED UPON THAT : IT IS 
PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT, FOR PURPOSE OF HAZARD 
COMMUNICATION. IT IS NOT INTENDED TO CONSTITUTE PRODUCT PERFORMANCE 
INFORMATION, AND NO EXPRESS OR IMPLIED WARRANTY OF ANY KIND IS MADE WITH 
RESPECT TO THE PRODUCT, UNDERLYING DATA OR THE INFORMATION CONTAINED HEREIN. 
YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL PRODUCTS YOU BUY, PROCESS, USE OR 
DISTRIBUTE, AND ARE ENCOURAGED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH 
SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN. 

TO DETERMINE THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT 
TO THE PRODUCT, YOU SHOULD CONSULT WITH YOUR LEGAL ADVISOR OR THE APPROPRIATE 
GOVERNMENT AGENCY. WE WILL NOT PROVIDE ADVICE ON SUCH MATTERS, OR BE 
RESPONSIBLE FOR ANY INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. THE 
UNDERLYING DATA, AND THE INFORMATION PROVIDED HEREIN AS A RESULT OF THAT DATA, 
IS THE PROPERTY OF MOTIVA ENTERPRISES LLC AND IS NOT TO BE THE SUBJECT OF SALE 
OR EXCHANGE WITHOUT THE EXPRESS WRITTEN CONSENT OF MOTIVA ENTERPRISES LLC.

44156-11800-100R-04/05/2005